330-13-2|pNNP|4-nitrophenyl dihydrogen phosphate|-范德生物科技公司

pNNP

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names：
4-nitrophenyl dihydrogen phosphate
CAS号：
330-13-2
MDL Number：
MF(分子式)： C6H6NO6P MW(分子量)： 219.08
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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询价

中文别名	4-nitrophenyl dihydrogen phosphate
英文别名	pNNP; p-NNP; p NNP; p-Nitrophenyl phosphate;
CAS号	330-13-2
SMILES	O=P(O)(OC1=CC=C([N+]([O-])=O)C=C1)O
Inchi	InChI=1S/C6H6NO6P/c8-7(9)5-1-3-6(4-2-5)13-14(10,11)12/h1-4H,(H2,10,11,12)
InchiKey	XZKIHKMTEMTJQX-UHFFFAOYSA-N
分子式 Formula	C6H6NO6P
分子量 Molecular Weight	219.08
闪点 FP
熔点 Melting point
沸点 Boiling point
Polarizability极化度
密度 Density
蒸汽压 Vapor Pressure
溶解度Solubility
性状	Solid powder
储藏条件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

产品说明	pNNP(CAS:330-13-2):仅限应用于工业或者科学研究过程中非医疗目的，不应用于人类或动物的临床诊断以及治过程疗，该产品非药用，非食用。
Introduction	pNNP is used as a substrate instead of phosphorylated proteins in the PP2C assay.
Application1
Application2
Application3

警示图
危险性	Warning
危险性警示
安全声明
安全防护
备注

[1]Demmans KZ, Seo CSG, Lough AJ, Morris RH. From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP' precatalysts for the asymmetric transfer hydrogenation of acetophenone. Chem Sci. 2017 Sep 1;8(9):6531-654[1]doi: 10.1039/c7sc02558k. Epub 2017 Jul 14. PubMed PMID: 28989679; PubMed Central PMCID: PMC5627452.

[2]Li YY, Yu SL, Shen WY, Gao JX. Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones. Acc Chem Res. 2015 Sep 15;48(9):2587-98. doi: 10.1021/acs.accounts.5b00043. Epub 2015 Aug 24. PubMed PMID: 26301426.

[3] Kumar S, Mani G, Dutta D, Mishra S. Structural diversity of copper(I) complexes formed by pyrrole- and dipyrrolylmethane-based diphosphine ligands with cu-X···HN hydrogen bonds. Inorg Chem. 2014 Jan 21;53(2):700-9. doi: 10.1021/ic402253y. Epub 2014 Jan 3. PubMed PMID: 24392950.

[4] Kumar S, Mani G, Mondal S, Chattaraj PK. Pyrrole-based new diphosphines: Pd and Ni complexes bearing the PNP pincer ligand. Inorg Chem. 2012 Nov 19;51(22):12527-39. doi: 10.1021/ic301967r. Epub 2012 Nov 8. PubMed PMID: 23137009.

[5] Mikhailine AA, Maishan MI, Morris RH. Asymmetric transfer hydrogenation of ketimines using well-defined iron(II)-based precatalysts containing a PNNP ligand. Org Lett. 2012 Sep 7;14(17):4638-41. doi: 10.1021/ol302079q. Epub 2012 Aug 27. PubMed PMID: 22924839.

6: Mikhailine AA, Maishan MI, Lough AJ, Morris RH. The mechanism of efficient asymmetric transfer hydrogenation of acetophenone using an iron(II) complex containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 ligand: partial ligand reduction is the key. J Am Chem Soc. 2012 Jul 25;134(29):12266-80. doi: 10.1021/ja304814s. Epub 2012 Jul 13. PubMed PMID: 22793266.7: Sonnenberg JF, Coombs N, Dube PA, Morris RH. Iron nanoparticles catalyzing the asymmetric transfer hydrogenation of ketones. J Am Chem Soc. 2012 Apr 4;134(13):5893-9. doi: 10.1021/ja211658t. Epub 2012 Mar 26. PubMed PMID: 22448656.8: Schotes C, Althaus M, Aardoom R, Mezzetti A. Asymmetric Diels-Alder and Ficini reactions with alkylidene β-ketoesters catalyzed by chiral ruthenium PNNP complexes: mechanistic insight. J Am Chem Soc. 2012 Jan 18;134(2):1331-43. doi: 10.1021/ja210372u. Epub 2012 Jan 6. PubMed PMID: 22191539.9: Schotes C, Mezzetti A. Enantioselective Diels-Alder reactions of unsaturated beta-ketoesters catalyzed by chiral ruthenium PNNP complexes. Chimia (Aarau). 2011;65(4):231-4. PubMed PMID: 21678768.10: Lagaditis PO, Lough AJ, Morris RH. Low-valent ene-amido iron complexes for the asymmetric transfer hydrogenation of acetophenone without base. J Am Chem Soc. 2011 Jun 29;133(25):9662-5. doi: 10.1021/ja202375y. Epub 2011 Jun 7. PubMed PMID: 21627152.1

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