9003-07-0|聚丙烯|Ppolypropylene|MFCD00084447-范德生物科技公司

聚丙烯
NMR and HPLC COA下载 MSDS下载
Names：
Ppolypropylene
CAS号：
9003-07-0
MDL Number： MFCD00084447
MF(分子式)： [CH2CH(CH3)]n MW(分子量)： 354.6克/摩尔
EINECS:618-352-4 Reaxys Number:No data available
Pubchem ID:76958 Brand:BIOFOUNT

聚丙烯(Polypropylene,9003-07-0,PP)是一种半结晶的热塑性塑料。具有较高的耐冲击性，机械性质强韧，抗多种有机溶剂和酸碱腐蚀。在工业界有广泛的应用，包括包装材料和标签，纺织品（例如，绳，保暖内衣和地毯），文具，塑料部件和各种类型的可重复使用的容器，实验室中使用的热塑性聚合物设备，扬声器，汽车部件，和聚合物纸币，是平常常见的高分子材料之一。在2013年，聚丙烯全球市场约55万吨。澳大利亚和加拿大的塑料钱币也使用聚丙烯制作。聚丙烯是棕褐色至白色的无味固体。比水密度低，不溶于水。因此漂浮在水上。聚丙烯是低密度，低粘度的均聚物。聚丙烯是为减少结块，划痕和磨损的蜡改性剂。改善聚丙烯膜和纤维中颜料的分散性。

货品编码	规格	纯度	价格 (¥)	现价(¥)	特价(¥)	库存描述	数量	总计 (¥)
CG0266-500g	500g	熔融指数 0.5g/10min	¥ 196.00	¥ 196.00		3-5days	- +	¥ 0.00

大包装询价提供各种包装，敬请垂询
收藏商品商品点评加入购物车立即购买

快速询价

收起

你想询价的产品

*产品名称：

CAS号：

产品编号：

需求描述：

请准确填写您的联系方式，以便为您提供最好的服务。

*公司名称：

*电子邮箱：

联系人：

*电话：

*验证码：

询价

中文别名	聚丙烯(9003-07-0),丙纶油剂; PP; 丙纶; 丙纶短纤维; 丙纶长丝FDY; 丙纶FDY; 丙纶短纤;塞尔加德;均聚物聚丙烯;
英文别名	Polypropylene(9003-07-0),poly(propylene);celgard;
CAS号	9003-07-0
SMILES	CCCCCCCCC1C（O1）CCCCCCCCCCCCCC（= O）O
Inchi	InChI = 1S / C22H42O3 / c1-2-3-4-5-11-14-17-20-21（25-20）18-15-12-9-7-6-8-10-13-16- 19-22（23）24 / h20-21H，2-19H2,1H3，（H，23,24）/ t20-，21 + / m1 / s1
InchiKey	NSYDMBURIUSUDH-RTWAWAEBSA-N
分子式 Formula	[CH2CH(CH3)]n
分子量 Molecular Weight	354.6克/摩尔
闪点 FP	151.6±14.7°摄氏度
熔点 Melting point	189°C(lit.)
沸点 Boiling point	120-132 °C，760毫米汞柱时475.0±18.0°C
Polarizability极化度	No data available
密度 Density	0.9在68°F，0.9±0.1克/厘米3
蒸汽压 Vapor Pressure	25°C时为0.0±2.5 mmHg
溶解度Solubility	溶胶HOT 萘烷和四氢化萘，沸腾四氯乙烷/等静液形式的溶胶，实际上在冷的有机溶剂中溶解/等渗形式/
性状	棕褐色至白色的无味固体或粒子（球形）
储藏条件 Storage conditions	20°C室温保存

聚丙烯(Polypropylene,9003-07-0,PP)毒理性质:

生物	测试类型	路线	报告剂量（标准化剂量）	影响	资源
rat	LD50	intraperitoneal	> 110gm/kg (110000mg/kg)	SENSE ORGANS AND SPECIAL SENSES: PTOSIS: EYE	Yakuri to Chiryo. Pharmacology and Therapeutics. Vol. 14, Pg. 1109, 1986.

				BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

				SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE
rat	LD50	intravenous	> 99gm/kg (99000mg/kg)	LUNGS, THORAX, OR RESPIRATION: CYANOSIS	Yakuri to Chiryo. Pharmacology and Therapeutics. Vol. 14, Pg. 1109, 1986.

				BEHAVIORAL: TREMOR

聚丙烯在医疗设备在短时间放置到连接或肌肉组织中时，不会产生轻微或无刺激性的响应。对于聚丙烯扩散的可渗透性材料非常小，无法检测到生物反应。完全聚合且不含小分子WT COMPD的塑料通常是惰性的，对眼睛没有明显的毒性，但实际上，它们是小异物，可能在结膜囊或角膜内引起刺激。储存在特定聚丙烯容器中的大容量注入产品未曾提出任何不良问题，也未发现任何会产生毒性反应的污染物。在250℃以上的热应力条件下，这些聚烯烃会降解为刺激性和伤害性的化合物。危害与与任何有机材料燃烧有关的危害没有很大不同。
一般而言，有毒影响归因于塑料的制造，可能会持久化并污染制成品，或者可能归因于分解产品或塑料增塑剂。

聚丙烯(Polypropylene,9003-07-0,PP)实验注意事项：
1.实验前需戴好防护眼镜，穿戴防护服和口罩，佩戴手套，避免与皮肤接触。
2.实验过程中如遇到有毒或者刺激性物质及有害物质产生，必要时实验操作需要手套箱内完成以免对实验人员造成伤害。
3.取样品的移液枪头需及时更换，必要时为避免交叉污染尽可能选择滤芯吸头。
4.称量药品时选用称量纸，并无风处取药和称量以免扬撒，试剂的容器使用前务必确保干净，并消毒。
5.取药品时尽量采用多个药勺分别使用，使用后清洗干净后，烘干消毒存放。
6.实验后产生的废弃物需分类存储，并交于专业生物废气物处理公司处理，以免造成环境污染。
Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.

Tags：聚丙烯试剂,聚丙烯杂质,聚丙烯中间体,聚丙烯密度,聚丙烯旋光度,聚丙烯合成,聚丙烯闪点,聚丙烯MSDS,聚丙烯结构式,聚丙烯蒸气压,聚丙烯分子式,

产品说明	聚丙烯(9003-07-0,PP)是棕褐色至白色的无味固体.聚丙烯比水密度低,聚丙烯不溶于水,因此漂浮在水上.聚丙烯,溶解度,聚丙烯MSDS详见主页
Introduction	聚丙烯(Polypropylene,9003-07-0,PP)is a brown to white odorless solid. It is less dense than water and insoluble in water. So floating on the water.
Application1	聚丙烯是通过丙烯和乙烯的单体形成长链而制得的，校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他
Application2	聚丙烯是棕褐色至白色的无味固体。比水密度低，不溶于水。因此漂浮在水上。
Application3	聚丙烯是一种半结晶的热塑性塑料。具有较高的耐冲击性，机械性质强韧，抗多种有机溶剂和酸碱腐蚀。

聚丙烯(Polypropylene,9003-07-0,PP)药理学：

※聚丙烯是棕褐色至白色的无味固体。比水密度低，不溶于水。因此漂浮在水上。

※聚丙烯是一种半结晶的热塑性塑料。具有较高的耐冲击性，机械性质强韧，抗多种有机溶剂和酸碱腐蚀。

※在工业界有广泛的应用，包括包装材料和标签，纺织品（例如，绳，保暖内衣和地毯），文具，塑料部件和各种类型的可重复使用的容器，实验室中使用的热塑性聚合物设备，扬声器，汽车部件，和聚合物纸币，是平常常见的高分子材料之一。在2013年，聚丙烯全球市场约55万吨。澳大利亚和加拿大的塑料钱币也使用聚丙烯制作。

※聚丙烯是低密度，低粘度的均聚物。聚丙烯是为减少结块，划痕和磨损的蜡改性剂。改善聚丙烯膜和纤维中颜料的分散性。聚丙烯网层压有未增强的硫化硅橡胶片。丙烯或丙烯聚合物。可以挤出成纤维，薄膜或固体形式的热塑性塑料。它们被用作塑料特别是聚乙烯的共聚物。纤维用于织物，过滤器和外科缝合线。聚丙烯网，层压有未增强的硫化硅橡胶片。

警示图
危险性
危险性警示	无明显毒性，可燃易燃性与羊毛相当，但燃烧缓慢。灭火剂可灭火：泡沫，干粉，二氧化碳
安全声明	No data available
安全防护	H303吞入可能有害+H313皮肤接触可能有害+H333吸入可能对身体有害
备注	P264处理后彻底清洗+P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具+P305如果进入眼睛+P351用水小心冲洗几分钟+P338取出隐形眼镜（如果有）并且易于操作,继续冲洗+P337如果眼睛刺激持续+P313获得医疗建议/护理

聚丙烯(Polypropylene,9003-07-0,PP)危害标识：
化学：聚丙烯(Polypropylene,9003-07-0,PP)无明显毒性

The respiratory effects of occupational polypropylene flock exposure S Atis 1, B Tutluoglu, E Levent, C Ozturk, A Tunaci, K Sahin, A Saral, I Oktay, A Kanik, B Nemery Affiliations expand PMID: 1564033

Effects of membrane type and liquid/liquid phase boundary on in vitro release of ketoprofen from gel formulations,Simon J Gallagher 1, Lionel Trottet, Timothy P Carter, Charles M Heard Affiliations ex

Bio-Polyethylene (Bio-PE), Bio-Polypropylene (Bio-PP) and Bio-Poly(ethylene terephthalate) (Bio-PET): Recent Developments in Bio-Based Polymers Analogous to Petroleum-Derived Ones for Packaging and En

A Review on Porous Polymeric Membrane Preparation. Part II: Production Techniques with Polyethylene, Polydimethylsiloxane, Polypropylene, Polyimide, and Polytetrafluoroethylene PMID 31387315; Polymers

Supercritical fluid extraction for purification of waxes derived from polyethylene and polypropylene plastics PMID 31447020; Waste management (New York, N.Y.) 2019 Sep; 97:131-139

聚丙烯(Polypropylene,9003-07-0,PP)参考文献：

1. [抗冲聚丙烯共聚物二甲苯可溶物的链结构和热性能研究]。
Luo HL1, Zhao Y, Wu JG, Wang DJ. Guang Pu Xue Yu Guang Pu Fen Xi. 2012 Dec;32(12):3363-6.
Impact polypropylene copolymers (IPC) are in-situ blends of polypropylene homopolymer and ethylene-alpha-olefin copolymers formed in the reactor, which is a multiphasic complex material with isotactic polypropylene (iPP) as a matrix in which poly(ethylene-alpha-olefin) elastomeric copolymer is finely dispersed, and ethylene-alpha-olefin random copolymer (EPR) acts as an elastomer to improve the impact resistance properties of iPP at room temperature and low temperature. In the present, the content of xylene soluble is used to evaluate the content of EPR rubber phase in IPC. The content, the chain structure, and glass transition temperature (T(g)) of EPR rubber are critical to the toughness of IPC. In the present report, Fourier transform infrared spectroscopy(FTIR), nuclear magnetic resonance (NMR) and differential scanning calorimetry(DSC) were utilized to study the comonomer content, chain structure and thermal property of xylene soluble of two IPC prepared by different catalysts.

2.均聚物的相容性：通过添加少量的PVAc，可显着提高PPC / PMMA混合物的模量和拉伸强度。
Li Y1, Shimizu H. ACS Appl Mater Interfaces. 2009 Aug;1(8):1650-5. doi: 10.1021/am900314k.
Poly(propylene carbonate) (PPC), a polymer produced from CO2, has been melt-mixed with 30 wt % poly(methyl methacrylate) (PMMA) with the aim of enhancing the physical properties of PPC for practical use but keeping a relatively high CO2 fixing rate in the compound. The observation of a coarse phase structure with a large PMMA domain size and a large size distribution in the blend indicates the immiscibility between PPC and PMMA. The addition of a small amount of poly(vinyl acetate) (PVAc) not only shifts the glass transition temperatures (T(g)'s) of both PPC and PMMA markedly but also significantly increases the modulus and tensile strength of the blend. The prepared compound with 5 per hundred parts of resin PVAc shows a 26 times higher elastic modulus and an approximately 3.8 times higher tensile strength than pure PPC at room temperature. The morphological investigation indicates that the incorporation to PVAC not only induces the finer dispersion of PMMA in the PPC matrix but also results in the phase transformation from a sea-island to a co-continuous structure.

3，螺旋均聚物晶体的非径向生长：打破了聚合物球晶微观结构的范式。
Rosenthal M1, Hernandez JJ, Odarchenko YI, Soccio M, Lotti N, Di Cola E, Burghammer M, Ivanov DA. Macromol Rapid Commun. 2013 Dec;34(23-24):1815-9. doi: 10.1002/marc.201300713. Epub 2013 Nov 8.
Radial symmetry is essential for the conventional view of the polymer spherulite microstructure. Typically it is assumed that, in the course of the spherulite morphogenesis, the lamellar crystals grow radially. Using submicron X-ray diffraction, it is shown that in banded spherulites of poly(propylene adipate) the crystals have the shape of a helix with flat-on crystals winding around a virtual cylinder of about 6 µm in diameter. The helix angle of 30° implies that the crystal growth direction is tilted away from the spherulite radius by this angle. The implications of the helical crystal shape contradict the paradigm of the spherulitic microstructure. The radial growth rate of such spherulites does not correspond to the crystal growth rate, but to the propagation rate of the virtual cylinder the ribbons wind around.

4，结合TREF，高温HPLC，FTIR和HPer DSC进行复杂聚丙烯共聚物的综合分析。
Cheruthazhekatt S1, Pijpers TF, Mathot VB, Pasch H. Anal Bioanal Chem. 2013 Nov;405(28):8995-9007. doi: 10.1007/s00216-013-6955-5. Epub 2013 Apr 24.
A novel, powerful analytical technique, preparative temperature rising elution fractionation (prep TREF)/high-temperature (HT)-HPLC/Fourier transform infrared spectroscopy (FTIR)/high-performance differential scanning calorimetry (HPer DSC)), has been introduced to study the correlation between the polymer chain microstructure and the thermal behaviour of various components in a complex impact polypropylene copolymer (IPC). For the comprehensive analysis of this complex material, in a first step, prep TREF is used to produce less complex but still heterogeneous fractions. These chemically heterogeneous fractions are completely separated by using a highly selective chromatographic separation method--high-temperature solvent gradient HPLC. The detailed structural and thermal analysis of the HPLC fractions was conducted by offline coupling of HT-HPLC with FTIR spectroscopy and a novel DSC method--HPer DSC. Three chemically different components were identified in the mid-elution temperature TREF fractions.

对不起，暂无产品评价！

MSDS

SDS 1.0 中文

展开

SDS 1.0 英文

展开