26002-80-2|苯醚菊酯|Phenothrin|MFCD00078716-范德生物科技公司

苯醚菊酯

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names：
Phenothrin
CAS号：
26002-80-2
MDL Number： MFCD00078716
MF(分子式)： C23H26O3 MW(分子量)： 350.45
EINECS:247-431-2 Reaxys Number:
Pubchem ID:4767 Brand:BIOFOUNT

苯醚菊酯(26002-80-2,Phenothrin)是淡黄色至黄棕色液体，无腐蚀性。苯醚菊酯是环丙烷羧酸酯。苯醚菊酯具有拟除虫菊酯杀虫剂的作用。苯醚菊酯衍生自菊花酸。

货品编码	规格	纯度	价格 (¥)	现价(¥)	特价(¥)	库存描述	数量	总计 (¥)
YZM000803-200mg	200mg	>95%	¥ 0.00	¥ 0.00		Backorder	- +	¥ 0.00
YZM000803-100mg	100mg	>95%	¥ 488.00	¥ 488.00		Backorder	- +	¥ 0.00

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中文别名	苯醚菊酯(26002-80-2,Phenothrin);苯氧司林;苯诺茨林;酚丁灭虱;聚醚菊酯
英文别名	Phenothrin(26002-80-2);Sumithrin;Phenoxythrin;Pibutin
CAS号	26002-80-2
SMILES	O=C(C1C(C)(C)C1/C=C(C)\C)OCC2=CC=CC(OC3=CC=CC=C3)=C2
Inchi	InChI=1S/C23H26O3/c1-16(2)13-20-21(23(20,3)4)22(24)25-15-17-9-8-12-19(14-17)26-18-10-6-5-7-11-18/h5-14,20-21H,15H2,1-4H3
InchiKey	SBNFWQZLDJGRLK-UHFFFAOYSA-N
分子式 Formula	C23H26O3
分子量 Molecular Weight	350.45
闪点 FP	186.6±23.3 °C
熔点 Melting point	25°C
沸点 Boiling point	437.0±45.0 °C at 760 mmHg
Polarizability极化度	41.7±0.5 10-24cm3
密度 Density	1.1±0.1 g/cm3
蒸汽压 Vapor Pressure	0.0±1.0 mmHg at 25°C
溶解度Solubility
性状	浅黄色至黄棕色液体
储藏条件 Storage conditions	存放在阴凉干燥处，短期（数天至数周）在0-4℃，长期（数月至数年）在-20℃。

苯醚菊酯(26002-80-2,Phenothrin)毒性测试：

生物	测试类型	路线	报告剂量（标准化剂量）	参考
mouse	LD50	intraperitoneal	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
mouse	LD50	intravenous	354mg/kg (354mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
mouse	LD50	oral	10gm/kg (10000mg/kg)	Yakkyoku. Pharmacy. Vol. 32, Pg. 47, 1981.
mouse	LD50	skin	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
mouse	LD50	subcutaneous	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
quail	LD50	oral	> 2150mg/kg (2150mg/kg)	Pesticide Manual. Vol. 9, Pg. 667, 1991.
rat	LD50	intraperitoneal	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
rat	LD50	intravenous	354mg/kg (354mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
rat	LD50	oral	> 10gm/kg (10000mg/kg)	Yakkyoku. Pharmacy. Vol. 37, Pg. 1481, 1986.
rat	LD50	skin	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.
rat	LD50	subcutaneous	> 5gm/kg (5000mg/kg)	Japan Pesticide Information. Vol. (37), Pg. 30, 1980.

苯醚菊酯(26002-80-2,Phenothrin)实验注意事项：
1.实验前需戴好防护眼镜，穿戴防护服和口罩，佩戴手套，避免与皮肤接触。
2.实验过程中如遇到有毒或者刺激性物质及有害物质产生，必要时实验操作需要手套箱内完成以免对实验人员造成伤害
3.实验后产生的废弃物需分类存储，并交于专业生物废气物处理公司处理，以免造成环境污染

Phenothrin(26002-80-2) Experimental considerations:
1. Wear protective glasses, protective clothing and masks, gloves, and avoid contact with the skin during the experiment.
2. The waste generated after the experiment needs to be stored separately, and handed over to a professional biological waste gas treatment company to avoid environmental pollution.

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产品说明	苯醚菊酯(26002-80-2,Phenothrin)是环丙烷羧酸酯。苯醚菊酯具有拟除虫菊酯杀虫剂的作用。
Introduction	Phenothrin (26002-80-2, 苯醚菊酯) is a cyclopropane carboxylate. Phenothrin has the effect of pyrethroid insecticides.
Application1
Application2
Application3

警示图
危险性	warning
危险性警示	Not available
安全声明	H303吞入可能有害+H313皮肤接触可能有害+H2413吸入可能对身体有害
安全防护	P264处理后彻底清洗+P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具+P305如果进入眼睛+P351用水小心冲洗几分钟+P338取出隐形眼镜（如果有）并且易于操作,继续冲洗+P337如果眼睛刺激持续+P2393获得医疗建议/护理
备注	实验过程中防止吸入、食入，做好安全防护

象形图
信号警告	Warning
GHS危险说明	Aggregated GHS information provided by 186 companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. Reported as not meeting GHS hazard criteria by 8 of 186 companies. For more detailed information, please visit ECHA C&L website Of the 7 notification(s) provided by 178 of 186 companies with hazard statement code(s): H302 (96.63%): Harmful if swallowed [Warning Acute toxicity, oral] H312 (96.63%): Harmful in contact with skin [Warning Acute toxicity, dermal] H332 (96.07%): Harmful if inhaled [Warning Acute toxicity, inhalation] H400 (99.44%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard] H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard] Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
防范说明代码	P261, P264, P270, P271, P273, P280, P301+P312, P302+P352, P304+P312, P304+P340, P312, P322, P330, P363, P391, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.)

Electrochemical Determination of Phenothrin in Agricultural Formulations, Vegetables, and Storage Bags of Wheat and Rice by Differential Pulse Adsorptive Stripping Voltammetry (DP-AdSV)

A Comparison of the Toxicity of Synergized and Technical Formulations of Permethrin, Sumithrin, and Resmethrin to Trout(Archives of Environmental Contamination and Toxicology,2005)

Pyrethroid Metabolism: Studies on Cis- and Trans-Phenothrins, and Related Epoxide Intermediates(Toxic Interfaces of Neurones, Smoke and Genes,1986)

Kinetics and Photophysical Mechanism of Sunlight Photolysis of Unstable Resmethrin and Phenothrin in Aerosols and Thin Films

The photochemical behaviour of five household pyrethroid insecticides and a synergist as studied by photo-solid-phase microextraction

1.Asymmetric syntheses and bio-evaluation of novel chiral esters derived from substituted tetrafluorobenzyl alcohol.
Xu S1, Li H1, Wang X1, Chen C1, Cao M1, Cao X2. Bioorg Med Chem Lett. 2014 Jun 15;24(12):2734-6. doi: 10.1016/j.bmcl.2014.04.055. Epub 2014 Apr 21.
A series of novel chiral esters derived from tetrafluorobenzyl alcohol were designed and prepared via asymmetric synthesis. The target molecules have been identified on the basis of analytical spectra data. All newly synthesized compounds have been screened their potential insecticidal activity against Plutella xylostella compared with those of fenvalerate and d-trans-phenothrin by standard method, and the respective pairs of enantiomers (3-B1-R/S, 3-C1-R/S, 3-D1-R/S) indicated significantly different activities.

2.Susceptibility of Adult Cat Fleas (Siphonaptera: Pulicidae) to Insecticides and Status of Insecticide Resistance Mutations at the Rdl and Knockdown Resistance Loci.
Rust MK1, Vetter R, Denholm I, Blagburn B, Williamson MS, Kopp S, Coleman G, Hostetler J, Davis W, Mencke N, Rees R, Foit S, Böhm C, Tetzner K. Parasitol Res. 2015 Aug;114 Suppl 1:S7-18. doi: 10.1007/s00436-015-4512-1.
The susceptibility of 12 field-collected isolates and 4 laboratory strains of cat fleas, Ctenocephalides felis was determined by topical application of some of the insecticides used as on-animal therapies to control them. In the tested field-collected flea isolates the LD50 values for fipronil and imidacloprid ranged from 0.09 to 0.35 ng/flea and 0.02 to 0.19 ng/flea, respectively, and were consistent with baseline figures published previously. The extent of variation in response to four pyrethroid insecticides differed between compounds with the LD50 values for deltamethrin ranging from 2.3 to 28.2 ng/flea, etofenprox ranging from 26.7 to 86.7 ng/flea, permethrin ranging from 17.5 to 85.6 ng/flea, and d-phenothrin ranging from 14.5 to 130 ng/flea. A comparison with earlier data for permethrin and deltamethrin implied a level of pyrethroid resistance in all isolates and strains. LD50 values for tetrachlorvinphos ranged from 20.0 to 420.0 ng/flea.

3.Susceptibility of field-collected mosquitoes in central New Jersey to organophosphates and a pyrethroid.
Sun D, Indelicato N, Petersen J, Williges E, Unlu I, Farajollahi A. J Am Mosq Control Assoc. 2014 Jun;30(2):138-42.
Chemical insecticides are the primary means to control mosquitoes, and mosquito control programs must regularly monitor for resistance of mosquito vectors to commonly used insecticides to ensure the efficacy and sustainability of active ingredients. We performed insecticide resistance bioassays to test the susceptibility of field-collected mosquitoes in central New Jersey to 1 larvicide (temephos) and 2 adulticides (malathion and sumithrin). Larval susceptibility of Culex pipiens pipiens to temephos provided median concentration (LC50) and 95% lethal concentration (LC95) values of 1.108 microg/l and 2.02 microg/l, respectively. Bottle bioassays of adult Aedes albopictus showed that 100% mortality was achieved at 35-min exposure to sumithrin and at 40-min to malathion. Baseline values were obtained using both temephos and sumithrin. Our bioassays indicate satisfactory susceptibility to temephos and sumithrin in Ae. albopictus and Cx. p. pipiens field populations in central New Jersey.

4.Comparison of phenothrin mousse, phenothrin lotion, and wet-combing for treatment of head louse infestation in the UK: a pragmatic randomised, controlled, assessor blind trial.
Burgess IF1, Brown CM1, Nair P2. F1000Res. 2014 Jul 10;3:158. doi: 10.12688/f1000research.2026.1. eCollection 2014.
In this investigation of effectiveness of an alternative pediculicide dosage form, we recruited 228 children and 50 adult participants from Bedfordshire, UK, to a randomised, controlled, assessor blind trial comparing two insecticide products with mechanical removal of lice as a control group. Participants using insecticide were treated with either the investigative 0.5% phenothrin mousse, for 30 minutes, or 0.2% phenothrin lotion, for 2 hours as the reference product. Both treatments were applied only once, followed by shampoo washing. Those treated by wet-combing with conditioner were combed 4 times over 12 days. Parents/carers carried out the treatments to mimic normal consumer use. The outcome measure was the absence of lice, 14 days after treatment for the insecticides, and up to 14 days after completion of combing. Intention to treat analysis of the outcomes for 275 participants showed success for phenothrin mousse in 21/105

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