90547-90-3|Avenacin A 1|Oleanan-29-al, 12,13-epoxy-3-((O-beta-D-glucopyranosyl-(1-2)-O-(beta-D-glucopyranosyl-(1-4))-alpha-L-arabinopyranosyl)oxy)-16,23-dihydroxy-21-((2-(methylamino)benzoyl)oxy)-, (3beta,4alpha,12beta,16beta,20beta,21beta)-|-范德生物科技公司

Avenacin A 1

NMR下载 COA and HPLC MSDS下载
names：
Oleanan-29-al, 12,13-epoxy-3-((O-beta-D-glucopyranosyl-(1-2)-O-(beta-D-glucopyranosyl-(1-4))-alpha-L-arabinopyranosyl)oxy)-16,23-dihydroxy-21-((2-(methylamino)benzoyl)oxy)-, (3beta,4alpha,12beta,16beta,20beta,21beta)-
CAS号：
90547-90-3
MDL Number：
MF(分子式)： C55H83NO21 MW(分子量)： 1094.26
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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中文别名	Avenacin A 1
英文别名	Avenacin A 1
CAS号	90547-90-3
Inchi	InChI=1S/C55H83NO21/c1-49(23-59)17-32-51(3,19-36(49)74-45(69)25-10-8-9-11-26(25)56-7)33(61)18-54(6)53(5)15-12-30-50(2,31(53)16-35-55(32,54)77-35)14-13-34(52(30,4)24-60)75-48-44(76-47-43(68)41(66)38(63)28(21-58)72-47)39(64)29(22-70-48)73-46-42(67)40(65)37(62)27(20-57)71-46/h8-11,23,27-44,46-48,56-58,60-68H,12-22,24H2,1-7H3/t27-,28+,29-,30+,31-,32+,33+,34+,35-,36+,37+,38-,39-,40+,41-,42+,43-,44-,46-,47-,48+,49-,50-,51+,52+,53-,54+,55-/m1/s1
InchiKey	SYXUBXTYGFJFEH-XKAKYSBSSA-N
分子式 Formula	C55H83NO21
分子量 Molecular Weight	1094.26
溶解度Solubility
性状	Solid powder
储藏条件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

产品说明	Avenacin A 1(CAS:90547-90-3):仅限应用于工业或者科学研究过程中非医疗目的，不应用于人类或动物的临床诊断以及治过程疗，该产品非药用，非食用。
Introduction	Avenacin A 1 is a biochemical.
Application1
Application2
Application3

警示图
危险性	Warning
危险性警示
安全声明
安全防护
备注

[1]Kemen AC, Honkanen S, Melton RE, Findlay KC, Mugford ST, Hayashi K, Haralampidis K, Rosser SJ, Osbourn A. Investigation of triterpene synthesis and regulation in oats reveals a role for β-amyrin in determining root epidermal cell patterning. Proc Natl Acad Sci U S A. 2014 Jun 10;111(23):8679-84. doi: 10.1073/pnas.140155311[1]Epub 2014 May 27. PubMed PMID: 24912185; PubMed Central PMCID: PMC4060722.

[2]Mugford ST, Louveau T, Melton R, Qi X, Bakht S, Hill L, Tsurushima T, Honkanen S, Rosser SJ, Lomonossoff GP, Osbourn A. Modularity of plant metabolic gene clusters: a trio of linked genes that are collectively required for acylation of triterpenes in oat. Plant Cell. 2013 Mar;25(3):1078-92. doi: 10.1105/tpc.113.110551. Epub 2013 Mar 26. Erratum in: Plant Cell. 2013 Sep;25(9):3632. PubMed PMID: 23532069; PubMed Central PMCID: PMC3634678.

[3] Owatworakit A, Townsend B, Louveau T, Jenner H, Rejzek M, Hughes RK, Saalbach G, Qi X, Bakht S, Roy AD, Mugford ST, Goss RJ, Field RA, Osbourn A. Glycosyltransferases from oat (Avena) implicated in the acylation of avenacins. J Biol Chem. 2013 Feb 8;288(6):3696-704. doi: 10.1074/jbc.M112.426155. Epub 2012 Dec 20. Erratum in: J Biol Chem. 2013 Jul 5;288(27):19644. PubMed PMID: 23258535; PubMed Central PMCID: PMC3567625.

[4] Kunii M, Kitahama Y, Fukushima EO, Seki H, Muranaka T, Yoshida Y, Aoyama Y. β-Amyrin oxidation by oat CYP51H10 expressed heterologously in yeast cells: the first example of CYP51-dependent metabolism other than the 14-demethylation of sterol precursors. Biol Pharm Bull. 2012;35(5):801-4. PubMed PMID: 22687421.

[5] Wegel E, Koumproglou R, Shaw P, Osbourn A. Cell type-specific chromatin decondensation of a metabolic gene cluster in oats. Plant Cell. 2009 Dec;21(12):3926-36. doi: 10.1105/tpc.109.072124. Epub 2009 Dec 29. PubMed PMID: 20040536; PubMed Central PMCID: PMC2814510.

6: Bednarek P, Osbourn A. Plant-microbe interactions: chemical diversity in plant defense. Science. 2009 May 8;324(5928):746-8. doi: 10.1126/science.1171661. PubMed PMID: 19423814.7: Mylona P, Owatworakit A, Papadopoulou K, Jenner H, Qin B, Findlay K, Hill L, Qi X, Bakht S, Melton R, Osbourn A. Sad3 and sad4 are required for saponin biosynthesis and root development in oat. Plant Cell. 2008 Jan;20(1):201-12. doi: 10.1105/tpc.107.056531. Epub 2008 Jan 18. PubMed PMID: 18203919; PubMed Central PMCID: PMC2254932.8: Collins CM, Murray PG, Denman S, Morrissey JP, Byrnes L, Teeri TT, Tuohy MG. Molecular cloning and expression analysis of two distinct beta-glucosidase genes, bg1 and aven1, with very different biological roles from the thermophilic, saprophytic fungus Talaromyces emersonii. Mycol Res. 2007 Jul;111(Pt 7):840-9. Epub 2007 Jun 2. PubMed PMID: 17664063.9: Qi X, Bakht S, Qin B, Leggett M, Hemmings A, Mellon F, Eagles J, Werck-Reichhart D, Schaller H, Lesot A, Melton R, Osbourn A. A different function for a member of an ancient and highly conserved cytochrome P450 family: from essential sterols to plant defense. Proc Natl Acad Sci U S A. 2006 Dec 5;103(49):18848-53. Epub 2006 Nov 21. PubMed PMID: 17124172; PubMed Central PMCID: PMC1656972.10: Mukhopadhyay B, Field RA. Synthesis of L-arabinose-containing fragments of the oat root saponin Avenacin A-1. Carbohydr Res. 2004 May 17;339(7):1285-91. PubMed PMID: 15113665.1

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