121350-99-0|Amphidinolide D|(1S,2E,6E,10S,12R,13S,14R,17R,19S,20E,24R,26S)-13,14,17,19-tetrahydroxy-7,10,12,19,20,24-hexamethyl-22-methylene-9,27-dioxabicyclo[24.1.0]heptacosa-2,6,20-triene-8,15-dione|-范德生物科技公司

Amphidinolide D

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names：
(1S,2E,6E,10S,12R,13S,14R,17R,19S,20E,24R,26S)-13,14,17,19-tetrahydroxy-7,10,12,19,20,24-hexamethyl-22-methylene-9,27-dioxabicyclo[24.1.0]heptacosa-2,6,20-triene-8,15-dione
CAS号：
121350-99-0
MDL Number：
MF(分子式)： C32H50O8 MW(分子量)： 562.74
EINECS: Reaxys Number:
Pubchem ID: Brand:BIOFOUNT

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中文别名	Amphidinolide D
英文别名	Amphidinolide D
CAS号	121350-99-0
Inchi	InChI=1S/C32H50O8/c1-19-13-20(2)15-28-27(40-28)12-10-8-9-11-21(3)31(37)39-24(6)16-22(4)29(35)30(36)26(34)17-25(33)18-32(7,38)23(5)14-19/h10-12,14,20,22,24-25,27-30,33,35-36,38H,1,8-9,13,15-18H2,2-7H3/b12-10+,21-11+,23-14+/t20-,22-,24+,25+,27+,28+,29+,30+,32+/m1/s1
InchiKey	PYXZGBVSQBXPDQ-VQFFCZPRSA-N
分子式 Formula	C32H50O8
分子量 Molecular Weight	562.74
溶解度Solubility
性状	Solid powder
储藏条件 Storage conditions	Dry, dark and store at 0-4℃ for short term (days to weeks) or -20℃ for long term (Store correctly 2-3years).

产品说明	Amphidinolide D(CAS:121350-99-0):仅限应用于工业或者科学研究过程中非医疗目的，不应用于人类或动物的临床诊断以及治过程疗，该产品非药用，非食用。
Introduction	Amphidinolide D is a powerful activator of actomyosin ATPase enhances skeletal muscle contraction.
Application1
Application2
Application3

警示图
危险性	Warning
危险性警示
安全声明
安全防护
备注

[1]Matsunaga K, Nakatani K, Ishibashi M, Kobayashi J, Ohizumi Y. Amphidinolide B, a powerful activator of actomyosin ATPase enhances skeletal muscle contraction. Biochim Biophys Acta. 1999 Mar 14;1427(1):24-32. PubMed PMID: 10082984.

[2]Lu L, Zhang W, Carter RG. Total synthesis of cytotoxic macrolide amphidinolide B1 and the proposed structure of amphidinolide B2. J Am Chem Soc. 2008 Jun 11;130(23):7253-5. doi: 10.1021/ja803012n. Epub 2008 May 20. Erratum in: J Am Chem Soc. 2008 Sep 3;130(35):11834. PubMed PMID: 18489095; PubMed Central PMCID: PMC2435505.

[3] Sidera M, Costa AM, Vilarrasa J. Iododesilylation of TIPS-, TBDPS-, and TBS-substituted alkenes in connection with the synthesis of amphidinolides B/D. Org Lett. 2011 Sep 16;13(18):4934-7. doi: 10.1021/ol2020187. Epub 2011 Aug 25. PubMed PMID: 21866884.

[4] Tsuda M, Kubota T, Sakuma Y, Kobayashi J. Biosynthetic study of amphidinolide B. Chem Pharm Bull (Tokyo). 2001 Oct;49(10):1366-7. PubMed PMID: 11605674.

[5] Gopalarathnam A, Nelson SG. Amphidinolide B: asymmetric synthesis of a C7-C20 synthon. Org Lett. 2006 Jan 5;8(1):7-10. PubMed PMID: 16381554.

6: Kobayashi J, Ishibashi M, Nakamura H, Ohizumi Y, Yamasu T, Hirata Y, Sasaki T, Ohta T, Nozoe S. Cytotoxic macrolides from a cultured marine dinoflagellate of the genus Amphidinium. J Nat Prod. 1989 Sep-Oct;52(5):1036-41. PubMed PMID: 2607346.7: Hara A, Morimoto R, Iwasaki Y, Saitoh T, Ishikawa Y, Nishiyama S. Total syntheses of amphidinolides B, G, and H. Angew Chem Int Ed Engl. 2012 Sep 24;51(39):9877-80. doi: 10.1002/anie.201204992. Epub 2012 Aug 24. PubMed PMID: 22927025.8: Zhang W, Carter RG, Yokochi AF. Unified synthesis of C19-C26 subunits of amphidinolides B1, B2, and B3 by exploiting unexpected stereochemical differences in Crimmins' and Evans' aldol reactions. J Org Chem. 2004 Apr 2;69(7):2569-72. PubMed PMID: 15049660; PubMed Central PMCID: PMC2430272.

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